Chlorine Gas Sensing Properties of ZnO-CaO Ceramics

The chlorine gas sensing properties of pure ZnO (PZ) and CaO-added ZnO (CAZ) ceramics with relative densities of 48–65% were investigated from 25–380°C in Cl₂ concentration range from 0.9 ppm to 20 ppm using air or N₂ as a carrier gas. In the entire temperature range, the conductivity of PZ and CAZ ceramics decreased by introducing Cl₂ gas. 3 mol% CAZ showed a Cl₂ sensitivity ((0)/(Cl₂)) of 10 for 0.9 ppm Cl₂ in air at 300°C, suggesting its usefulness for sensing of a low-concentration Cl₂ gas below 1 ppm. The CaO addition was found to decrease the Cl₂ sensitivity but to improve the recovery process after removing Cl₂ gas. These effects are attributed to changes in the amount and stability of adsorbed oxygen and to subsequent changes in Cl₂ adsorption behavior.