Selective Catalytic Reduction of NOx over H-ZSM-5 Under Lean Conditions Using Transient NH3 Supply |
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| Authors: | Mikaela Wallin Carl-Johan Karlsson Anders Palmqvist and Magnus Skoglundh |
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| Affiliation: | (1) Competence Centre for Catalysis Chalmers University of Technlogy, SE-412 96 Göteborg, Sweden;(2) Applied Surface Chemistry, Chalmers University of Technology, SE-412 96 Göteborg, Sweden;(3) Volvo Technology Corporation, SE-412 88 Göteborg, Sweden |
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| Abstract: | The selective catalytic reduction (SCR) of NO
x
over zeolite H-ZSM-5 with ammonia was investigated using in situ FTIR spectroscopy and flow reactor measurements. The adsorption of ammonia and the reaction between NO
x
, O2 and either pre-adsorbed ammonia or transiently supplied ammonia were investigated for either NO or equimolar amounts of NO and NO2. With transient ammonia supply the total NO reduction increased and the selectivity to N2O formation decreased compared to continuous supply. The FTIR experiments revealed that NO
x
reacts with ammonia adsorbed on Brønsted acid sites as NH4
+ ions. These experiments further indicated that adsorbed -NO2
– is formed during the SCR reaction over H-ZSM-5. |
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| Keywords: | selective catalytic reduction of NO
x
NH3-SCR ammonia transients H-ZSM-5 in situ FTIR |
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