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Fabrication of two sites hydrophobicity on cotton surface – a fluoropolymerization approach
Authors:Sourav Mondal  Sukanta pal  Rajaram Bal
Affiliation:1. Department of Chemistry, Sidho-Kanho-Birsha University, Purulia, India;2. Department of Conversion &3. Catalysis Division, CSIR - Indian Institute of Petroleum, Dehradun, India
Abstract:Cotton fabric on both surfaces was coated with polymerization of fluoromonomer followed by adsorption of fluorosurfactant by a new technique admicellar polymerization to obtain durable hydrophobicity. Water repellence properties were determined in terms of simple drop test contact angles. The coating on cotton fabric exhibited the right water contact angle of 137.23° and left contact angle 138.35° (an average value of 137.79°). However, the durability of the coatings was decreased after simple home laundering with a decrease in water contact angle value. The surface morphology was evaluated by scanning electron microscopy before and after polymerization. Beside this chemical composition on the cotton, the surface was evaluated by EDS analysis to determine the number of fluorine moieties deposited on the cotton surface by this technique.
Keywords:Admicellar polymerization  contact angle  fluoromonomer
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