Insights into High‐Temperature Uniaxial Compression Deformation Behavior of Ti3AlC2

We report on strain‐rate‐dependent compression deformation behavior of Ti₃AlC₂ at 1000°C–1200°C. At 1000°C and high strain rate (10^?2 or 10^?3 s^?1), Ti₃AlC₂ deforms in a nonplastic manner. Upon increasing temperature and reducing strain rate, Ti₃AlC₂ exhibits a limited plasticity. For instance, the true plastic strain at 1200°C and 10^?4 s^?1 is only 3%, beyond which strain softening following a short hardening regime occurs. The softening results from the formation of localized microvoids and microcracks. Decreasing the strain rate further to 10^?5 s^?1 at 1200°C, strain hardening instead of softening is identified. Under such conditions, the plastic strain remarkably increases, reaching a value as high as 27%. Postdeformation microstructural analyses of the dislocation configurations explicitly evidence the dislocation reactions, formation of hexagonal dislocation networks and dislocation entanglements. These account for the strain hardening. The extraordinary plasticity at 1200°C and 10^?5 s^?1 benefits from the initiation of nonbasal slip systems. Finally, a complete high‐temperature deformation scenario for nanolaminated Ti₃AlC₂ is elaborated.