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PP/POE/WGRT热塑性弹性体的制备及性能研究
引用本文:宋现芬,郎丰正,李帅,王宝祥,王兆波.PP/POE/WGRT热塑性弹性体的制备及性能研究[J].特种橡胶制品,2013(2):5-8.
作者姓名:宋现芬  郎丰正  李帅  王宝祥  王兆波
作者单位:青岛科技大学材料科学与工程学院
基金项目:山东省自然科学基金(ZR2012EMM002);青岛市科技发展计划项目(12-1-4-3-(9)-jch);山东省高等学校科技计划项目(J12LA15);高分子材料工程国家重点实验室开放课题基金资助(KF201303)
摘    要:采用动态硫化法制备了PP/POE/WGRT共混型热塑性弹性体(TPE),考察了PP/WGRT共混比、在PP相中填充POE以及动态硫化法对TPE力学性能的影响。结果表明,改变PP/WGRT共混比以及在PP相中填充POE均不能获得TPE;采用动态硫化法制备的PP/POE/WGRT TPE具有较好力学性能,且当DCP用量为3份时TPE力学性能最佳。FE-SEM观察结果表明,动态硫化法使得PP/POE/WGRT TPE的界面作用获得增强,力学性能获得改善。

关 键 词:聚丙烯  聚烯烃弹性体  胶粉  动态硫化法  力学性能

Preparation and Properties of Thermoplastic Elastomer based on PP/POE/WGRT Blends
SONG Xian-fen,LANG Feng-zheng,LI Shuai,WANG Bao-xiang,WANG Zhao-bo.Preparation and Properties of Thermoplastic Elastomer based on PP/POE/WGRT Blends[J].Special Purpose Rubber Products,2013(2):5-8.
Authors:SONG Xian-fen  LANG Feng-zheng  LI Shuai  WANG Bao-xiang  WANG Zhao-bo
Affiliation:(Qingdao University of Science & Technology,Qingdao 266042,China)
Abstract:Thermoplastic elastomers based on polypropylene/polyolefin elastomer/WGRT (PP/ POE/WGRT) blends were prepared by dynamic vulcanization, and influences of PP/WGRT blending ratios, POE and dynamic vulcanization on mechanical properties of PP/POE/WGRT blends were in- vestigated systemically. The results showed that the PP/WGRT TPE could not be prepared by verif- ying the PP/WGRT blending ratios and the addition of POE, however, the PP/POE/WGRT TPE with good mechanical properties were prepared successfully by dynamic vulcanization, and the me- chanical properties were the best when DCP dosage was 3 phr. The FE-SEM results showed that the dynamic vulcanization had improved the interface interaction between PP matrix and WGRT, and the mechanical properties of PP/POE/WGRT blends were improved.
Keywords:polypropylene  polyolefin elastomer  WGRT  dynamic vulcanization  mechanical property
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