Cure kinetics of high performance epoxy resin systems |
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Authors: | Jyong Sup Shim Weon Lee Jyongsik Jang |
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Affiliation: | (1) Department of Chemical Technology, Seoul National University, Sinlimdong Kwanakgu, 151-742 Seoul, Korea;(2) Polymer Composites Laboratory, Korea Institute of Science and Technology, Cheongryang, P.O. Box 131, 131 Seoul, Korea |
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Abstract: | Summary Isothermal cure kinetics ofEPON HPT 1071/DDS system have been performed by means of differential scanning calorimetry. The maximum cure rate and the extent of conversion at various DDS concentrations were studied as a function of cure temperature. Maximum cure rate increases with increasing cure temperature and DDS concentration. At various DDS concentrations, the maximum cure rate occured between 19–22% conversion. In order to evaluate the kinetic parameters, numerical calculations by means of a Newton-Raphson technique and experimental results obtained from the peak of reaction rate curve were undertaken. |
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