首页 | 本学科首页   官方微博 | 高级检索  
     

二吡啶胺为配体的新型镍配合物的合成及结构
引用本文:李丽,朱兵,程媛媛,邓元. 二吡啶胺为配体的新型镍配合物的合成及结构[J]. 山东化工, 2014, 0(1): 13-15
作者姓名:李丽  朱兵  程媛媛  邓元
作者单位:[1]济宁市环保局高新区分局,山东济宁272000 [2]山东能源临矿集团田庄煤矿,山东济宁272100 [3]杭州师范大学有机硅化学及材料技术教育部重点实验室,浙江杭州311121
摘    要:以2,2'-二吡啶胺(Hdpa)和对氨基苯甲酸钠(PABA为4-氨基苯甲酸阴离子)为原料,和氟化镍反应合成了一种新型的镍配合物[Ni(PABA)(Hdpa)2]F(CH3OH)。通过X-射线单晶衍射、红外光谱、元素分析、质谱(ESI),对该配合物进行了结构表征。晶体结构表明,该配合物为阴离子-阳离子型化合物。

关 键 词:镍配合物  晶体结构  阴阳离子配合物

Study on the Synthesis,Crystal Structure for a Novel Nickel Complexes with Dipyridylamine Ligands
LI Li,ZHU Bing,CHENG Yuan - yuan,DENG Yuan. Study on the Synthesis,Crystal Structure for a Novel Nickel Complexes with Dipyridylamine Ligands[J]. Shandong Chemical Industry, 2014, 0(1): 13-15
Authors:LI Li  ZHU Bing  CHENG Yuan - yuan  DENG Yuan
Affiliation:1. High -tech Industrial Department Zone Branch of Jining Environmental Protection Bureau, Jining 272000, China; 2. Shandong Linkuang Energy Group Tianzhuang Branch, Jining 272100, China; 3. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, China)
Abstract:A novel nickel (II) complexes with the formula of [ Ni (PABA) (Hdpa) 2 ] F ( C H3 OH ) ( where Hdpa is 2,2'- dipyridylamine, PABA is 4 -aminobenzoie acid anion) were synthesized and characterized by IR, elemental analysis, MS (ESI) and single crystal X - ray diffraction analysis. Single crystal structure reveals that the complex was a cation - anionic nickel complex.
Keywords:nickel complex  crystal structure  cation - anionic complex
本文献已被 CNKI 维普 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号