| 烷基酚异构体及碳数分布的LC-MS分析 |
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| 引用本文： | 张大华,陈立仁.烷基酚异构体及碳数分布的LC-MS分析[J].石油炼制与化工,2006,37(12):48-52. |
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| 作者姓名： | 张大华 陈立仁 |
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| 作者单位： | 1. 兰州润滑油研究开发中心,兰州,730060
2. 兰州化学物理研究所 |
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| 摘 要： | 分别在Lichrosorb5 RP8和Nova-Pak C18色谱柱上利用高效液相色谱（HPLC）对以邻位取代为主的烷基酚进行了分离分析，并分别对分离后的各组分用液相色谱-质谱联用（LC-MS）进行了确认。结果表明，在Lichrosorb5 RP8色谱柱上，烷基酚样品完全按照取代基链长进行分离，而在Nova-PakC18色谱柱上，烷基酚样品不但按取代基链长进行分离，而且不同位置取代的异构体也进一步得到了分离。
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| 关 键 词： | 烷基酚 分子结构 色谱-质谱法 色谱分离 分析方法 |
| 收稿时间： | 2006-03-07 |
| 修稿时间： | 2006-07-05 |
THE ANALYSIS OF ISOMER AND CARBON NUMBER DISTRIBUTION OF ALKYLPHENOL BY HPLC-MS |
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| Zhang Dahua,Chen Liren.THE ANALYSIS OF ISOMER AND CARBON NUMBER DISTRIBUTION OF ALKYLPHENOL BY HPLC-MS[J].Petroleum Processing and Petrochemicals,2006,37(12):48-52. |
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| Authors: | Zhang Dahua Chen Liren |
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| Abstract: | The alkyphenols mainly 2-substituted were separated and analyzed by HPLC with Liehrosorb5 RP8 and Nova-Pak C18 columns respectively. The analysis result showed that the components of alkylphenols were separated according to the chain length of the substituents by the former; the alkylphenols were separated not only according to the chain length,but also further separated according to the substituted isomer position by the latter. The separated components were confirmed by LC-MS. |
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| Keywords: | alkylphenol molecular structure chromatography-mass spectrometry chromatography separation analytical method |
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