| 新型含环己烯结构的联苯型聚醚酮的合成及表征(Ⅰ) |
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| 引用本文： | 王漓江,蹇锡高,张所信.新型含环己烯结构的联苯型聚醚酮的合成及表征(Ⅰ)[J].辽东学院学报(自然科学版),2000(1). |
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| 作者姓名： | 王漓江 蹇锡高 张所信 |
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| 作者单位： | 丹东纺织高等专科学校!丹东１１８００３(王漓江)，大连理工大学高分子材料系!大连１１６０１２(蹇锡高)，淮海工学院(张所信) |
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| 基金项目： | 国家自然科学基金资助项目!（59743019） |
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| 摘 要： | 合成了一种新型聚合单体１－甲基－４，５－二（４－氯代苯甲酰基）环己烯，并与对苯二酚经亲核取代反应，成功地合成了含环己烯结构的联苯型聚醚酮聚合物。用ＦＴ－ＩＲ、１Ｈ－ＮＭＲ、ＤＳＣ、Ｘ－射线衍射等方法对聚合物进行了表征，并研究了聚合物的溶解性能。结果表明，聚合物是一种具有较高的玻璃化温度的可溶性无规共聚物。聚合物含有不饱和双键结构，是一种反应性高分子。
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| 关 键 词： | 聚芳醚酮 环己烯结构 反应性高分子 合成 |
SYNTHESIS AND CHARACTERIZATION OF POLY(ARYL ELHER KETONE) FROM 1 - METHYL - 4, 5 - BIS(CHLOROBENZOYL) CYCLOHEXENE AND 4 - (3, 5 - DIMETHYL - 4 - HYDROXYPHENYL) - 2, 3 - PHTHAZIN - 1 - ONE |
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| Wang Lijiang,Jian Xigao.SYNTHESIS AND CHARACTERIZATION OF POLY(ARYL ELHER KETONE) FROM 1 - METHYL - 4, 5 - BIS(CHLOROBENZOYL) CYCLOHEXENE AND 4 - (3, 5 - DIMETHYL - 4 - HYDROXYPHENYL) - 2, 3 - PHTHAZIN - 1 - ONE[J].Journal of Liaodong University：Natural Sciences,2000(1). |
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| Authors: | Wang Lijiang Jian Xigao |
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| Abstract: | A novel poly (aryl ether ketone) containing the of cyclohexene and phthalazinone moieties polymer was prepared by the nucelophilic displacement reaction of 1 - methyl - 4, 5 - his(4 - chlorobenzoyl ) cyclohexene and 4 - (3, 5 - dimethyl - 4 - hydroxyphenyl) - 2, 3 - phthalazin - 1 -one. The polymer was studied by FT IR, H NMR, DSC, X ray diffraction. It has been proved that it was a amorphous plastics with high glass temperature(Tg = 216. 1℃). It was soluble in some solvents at room temperature. It was also intermediate product of cross - linked copolymer and grafted copolymer. |
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| Keywords: | poly (aryl ether ketone) cyclohexene heterocyclic polymer synthesis |
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