Coal hydrogenation: Quality of start-up solvents and partially process-derived recycle solvents |
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Authors: | Albert A. Awadalla David J. Cookson Brian E. Smith |
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Affiliation: | The Broken Hill Proprietary Co. Ltd, 245 Wellington Road, Mulgrave, Australia, 3170 |
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Abstract: | The performance of three sets of start-up solvents and one set of partially process-derived recycle solvents was studied in small autoclave coal hydrogenation tests. The start-up solvents were obtained by catalytically hydrotreating anthracene oils or creosote oils. It is shown that this preparation procedure converts polynuclear aromatics and two-ring aromatics to hydroaromatics and, ultimately, to alicyclics. Coal conversions using start-up solvents are found to reach a maximum at intermediate degrees of solvent hydrogenation which is believed to correspond to a maximal abundance of hydroaromatic solvent hydrogen donors. A solvent hydrogen donor index (SHDI), simply derived from 1H n.m.r. spectral data, was devised and is found to successfully correlate coal conversions obtained using different start-up solvents, especially where N2 gas rather than H2 gas is employed in the autoclave tests. A set of partially process-derived recycle solvents were produced in multiple cycle continuous coal hydrogenation experiments. These were tested under relatively severe hydrogenation conditions in the presence of hydrogen gas, using the small autoclave unit. Substantial donation of solvent hydrogen was found to occur and coal conversions to hexane — and toluene-soluble products are found to be a smooth function of the solvent hydrogen donor index. It is concluded that the hydrogen donor capacity of a solvent is a major factor governing coal conversion, especially when the demand for solvent hydrogen is high. The SHDI parameter is useful in rationalizing the behaviour of start-up solvents. Also, at least in the first few cycles of a continuous two stage coal hydrogenation process, the SHDI parameter allows solvent quality to be monitored, and consequently optimized. |
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Keywords: | coal hydrogenation solvents |
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