The production of fatty acid isopropyl esters and their use as a diesel engine fuel |
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Authors: | Paul?S?Wang Mustafa?E?Tat Email author" target="_blank">Jon?Van?GerpenEmail author |
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Affiliation: | (1) Mechanical Engineering Department, Osmangazi University, Bati Meselik/Eskisehi, Turkey;(2) Department of Biological and Agricultural Engineering Department, University of Idaho, 83844 Moscow, ID |
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Abstract: | Biodiesel is an alternative fuel for diesel engines that consists of the monoalkyl esters of vegetable oils or animal fats.
Currently, most biodiesel consists of methyl esters, which have poor cold-flow properties. Methyl esters of soybean oil will
crystallize and plug fuel filters and lines at about 0°C. However, isopropyl esters have better cold-flow properties than
methyl esters. This paper describes the production of isopropyl esters and their evaluation in a diesel engine. The effects
of the alcohol amount, the catalyst amount, and two different catalysts on producing quality biodiesel were studied. Both
sodium isopropoxide and potassium isopropoxide were found to be suitable for use in the transesterification process. A 20∶1
alcohol/TG molar ratio and a catalyst amount equal to 1% by weight (based on the TG amount) of sodium metal was the most cost-effective
way to produce biodiesel fuel. The emissions from a diesel engine running on isopropyl esters made from soybean oil and yellow
grease were investigated by comparing them with No. 2 diesel fuel and methyl esters. For nitrogen oxide emission, the difference
between the biodiesel produced from soybean oil and yellow grease was greater than the difference between the methyl and isopropyl
esters of both feedstocks. The other emissions from using isopropyl esters were about 50% lower in hydrocarbons, 10–20% lower
in carbon monoxide, and 40% lower in smoke number when compared with No. 2 diesel fuel. |
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Keywords: | Biodiesel diesel fuel isopropanol isopropyl esters |
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