|
|||||
|
|
| 羟化含氟嵌段共聚物的合成及其自组装行为研究 | |
| 引用本文： | 夏攀登,路翠苹,杜伯会,张书香.羟化含氟嵌段共聚物的合成及其自组装行为研究[J].胶体与聚合物,2008,26(2):32-34. |
| 作者姓名： | 夏攀登 路翠苹 杜伯会 张书香 |
| 作者单位： | 1. 山东省产品质量监督检验研究院,济南,250100 2. 济南市槐荫区房地产开发集团总公司,济南,250021 3. 济南大学化学化工学院,济南,250022 |
| 摘 要： | 用α-溴代丙酸乙酯（EPN—B）／氯化亚铜（CuCl）／联二吡啶（bpy）作为催化引发体系，环己酮为溶剂，进行甲基丙烯酸2，2，2-三氟乙酯（TFEMA）的原子转移自由基聚合（ATRP），得到单分散PTFEMA—X预聚体。并以此预聚体为大分子引发剂引发甲基丙烯酸-β-羟乙酯聚合，得到分子质量可控、分子质量分布窄的聚甲基丙烯酸2，2，2-三氟乙酯-b-聚甲基丙烯酸-β-羟乙酯嵌段共聚物，用FTIR、^1H—NMR、GPC等对产物的结构与性能进行了表征。同时利用动态激光光散射（DLS）对嵌段共聚物的自组装行为进行了研究。 |
| 关 键 词： | 原子转移自由基聚合 甲基丙烯酸2 2 2-三氟乙酯 嵌段共聚物 自组装 |
Synthesis and self-assembly behavior of fluorinated block copolymer containing hydroxylic groups |
|
| Xia Pandeng,Lu Cuiping,Du Bohui,Zhang Shuxiang.Synthesis and self-assembly behavior of fluorinated block copolymer containing hydroxylic groups[J].Chinese Journal of Colloid and Polymer,2008,26(2):32-34. | |
| Authors: | Xia Pandeng Lu Cuiping Du Bohui Zhang Shuxiang |
| Affiliation: | Xia Pandeng Lu Cuiping Du Bohui Zhang Shuxiang (1 Shandong Provincial Institute of Product Quality Supervision ＆ Inspection Jinan 250100; 2 Jinan Huaiyin District Real Estate Development Corporation Jinan 250021; 3 College of Chemistry and Chemical Engineering University of Jinan Jinan 250022) |
| Abstract: | This paper describes the application of atom transfer radical polymerization of 2,2,2-trifluo- roethylmethacrylate by using ethyl-2-bromopropionate (EPN-B/CuCl/bpy) as the initiating system and cyclo- hexanone as solvent.By using PTFEMA-X as the macroinitiator the well-defined poly(2,2,2-trifluoroethyl methacrylate)-b-poly (2-Hydroxyethyl methacrylate) diblock copolymer (PTFEMA-b-PHEMA) is prepared and characterized by ~1HNMR,FTIR and GPC.Furthermore,Self-assembly behavior of fluorinated block copolymer have been studied by DLS. |
| Keywords: | Atom transfer radical polymerization 2 2 2-Trifluoroethylmethacrylate Block copolymer self-assembly |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |