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NBR/CSM并用比对共混胶耐热耐油性能的影响
引用本文:赵妍,王娜,高雨,杨凤,韩文驰,方庆红.NBR/CSM并用比对共混胶耐热耐油性能的影响[J].弹性体,2013,23(1):48-52.
作者姓名:赵妍  王娜  高雨  杨凤  韩文驰  方庆红
作者单位:沈阳化工大学材料科学与工程学院,辽宁沈阳,110142
基金项目:国家自然科学基金,辽宁省自然科学基金
摘    要:研究了NBR/CSM并用比对共混胶硫化性能、力学性能、耐热老化性能和耐油性能的影响,并采用了扫描电镜分析方法表征共混胶浸油前后的结构。结果表明,随NBR用量的增加,共混胶的硫化效率提高,加工安全性能增强,耐油性能有所上升,但其耐热性能有所下降。当NBR/CSM并用比为60/40时,通过力学性能可知,共混胶中两相结构发生相反转。综合其性能,当NBR/CSM并用比为60/40时,共混胶具有最佳的耐热耐油性能,浸油后的抗拉强度保持率达到69%,断裂伸长率保持率达到86%,质量变化率为lO%,体积变化率为15%。

关 键 词:丁腈橡胶(NBR)  氯磺化聚乙烯橡胶(CSM)  并用  耐油性能  耐热性能

Study on the effects of NBR/CSM blending ratios on hot-air aging resistance and oil aging resistance of the blends
Zhao Yan , Wang Na , Gao Yu , Yang Feng , Han Wenchi , FANG Qinghong.Study on the effects of NBR/CSM blending ratios on hot-air aging resistance and oil aging resistance of the blends[J].China Elastomerics,2013,23(1):48-52.
Authors:Zhao Yan  Wang Na  Gao Yu  Yang Feng  Han Wenchi  FANG Qinghong
Affiliation:(Shenyang University of Chemical Technology,College of Material Science and Engineering,Shenyang 110142,China)
Abstract:The effects of NBR/CSM blending ratio on vulcanization,mechanical properties, hot-air oil aging resistance and oil aging resistance of the blends were studied, and scanning electron micro- scope(SEM)was used to characterize the structure of NBR/CSM blends before and after aging in the oil. The results showed that the vulcanizing efficiency and processing properties, hot-air oil aging re- sistance of NBR/CSM blends were improved with the increase of NBR content, but hot-air aging re- sistance of the blends was decreased. It was found that the phase inversion in blends occurred at the mass blending ratio of NBR/CSM was 60/40 by mechanical properties. The hot-air aging resistance and oil aging resistance of the blends were excellent when the blending ratio was 60/40, while keep rate of tensile strength after soaking in the oil reached 69%,keep rate of elongation at break reached 86 %, and change in mass after soaking in the oil reached 10%, change in volume reached 15%.
Keywords:nitrile rubber(NBR)  chlorosulfonated polyethylene rubber(CSM)  blending  oil agingresistance  hot-air aging resistance
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