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氯丁橡胶的老化和寿命预测研究
引用本文:王锋,董玉华,郭文娟,丁晓东,周琼.氯丁橡胶的老化和寿命预测研究[J].弹性体,2013,23(1):22-25.
作者姓名:王锋  董玉华  郭文娟  丁晓东  周琼
作者单位:1. 中国石油大学(北京)理学院材料科学与工程系,北京,102249
2. 中国船舶工业集团公司船舶系统工程部,北京,100094
基金项目:海军装备部重点科研项目
摘    要:通过对氯丁橡胶在55℃、70℃、85℃、100℃下热空气加速老化的实验,研究了氯丁橡胶的老化机理并进行了寿命预测。红外分析结果说明氯丁橡胶的老化机理为:热氧老化在C=C上进行;85℃、]00℃侧基C1脱离主链。以扯断伸长率为指标进行寿命预测,可知氯丁橡胶在本实验条件下的贮存寿命约为20a。

关 键 词:氯丁橡胶  热空气老化  寿命

Study on neoprene rubber aging and shelf-life predictions
Wang Feng , Dong Yuhua , Guo Wenjuan , Ding Xiaodong , Zhou Qiong.Study on neoprene rubber aging and shelf-life predictions[J].China Elastomerics,2013,23(1):22-25.
Authors:Wang Feng  Dong Yuhua  Guo Wenjuan  Ding Xiaodong  Zhou Qiong
Affiliation:1(1.Department of Material Science and Engineering,China University of Petroleum(Beijing) College of Science,Beijing 102249,China;2.China State Shipbuilding Corporation Ship Systems Engineering Department,Beijing 100094,China)
Abstract:The thermal oxidative aging properties of neoprene at 55 ℃, 70 ℃, 85 ℃, 100 ℃ were determined by using accelerated aging method at laboratory. The aging mechanism of chloroprene rub- ber was determined by IR:thermal aging on the C = C;85 ℃ ,100 ℃ the side groups C1 was away from the main chain. The relationship between properties and aging time of neoprene was established, and predicted at 25 ℃ neoprene storage life is twenty years.
Keywords:neoprene thermal oxidative aging aging
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