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新型磷-氮系复配阻燃剂在聚丙烯中的应用
引用本文:吴风磊,黄齐茂,陈云峰,万香港,潘志权.新型磷-氮系复配阻燃剂在聚丙烯中的应用[J].塑料科技,2011,39(12).
作者姓名:吴风磊  黄齐茂  陈云峰  万香港  潘志权
作者单位:1. 武汉工程大学化工与制药学院省部共建绿色化工过程教育部重点实验室,湖北武汉,430073
2. 国家磷资源开发利用工程技术研究中心,湖北武汉,430073
摘    要:采用一种新型磷-氮系阻燃剂与聚磷酸铵(APP)复配成膨胀型阻燃剂,对聚丙烯(PP)进行阻燃改性。研究了阻燃PP的阻燃性能、热分解过程及力学性能。结果表明:当复配阻燃剂添加量为30%时,阻燃改性PP的氧指数和垂直燃烧等级分别达到32.3%和UL94 V-0级,拉伸强度为37.4 MPa,缺口冲击强度为39.5 kJ/m2,并且具有很好的热稳定性。

关 键 词:磷-氮系阻燃剂  阻燃性能  聚丙烯

Application of Novel Phosphorus-Nitrogen Compounding Flame Retardant in PP
Wu Fenglei,Huang Qimao,Chen Yunfeng,Wan Xianggang,Pan Zhiquan.Application of Novel Phosphorus-Nitrogen Compounding Flame Retardant in PP[J].Plastics Science and Technology,2011,39(12).
Authors:Wu Fenglei  Huang Qimao  Chen Yunfeng  Wan Xianggang  Pan Zhiquan
Affiliation:Wu Fenglei1,Huang Qimao1,Chen Yunfeng1,Wan Xianggang1,Pan Zhiquan2 1 Key Laboratory for Green Chemical Process of Ministry of Education,School of Chemical Engineering and Pharmacy,Wuhan Institute of Technology,Wuhan 430073,China 2 National Phosphor Resources Development and Utilization Engineering Research Center,China
Abstract:Polypropylene(PP) was fire retarded by intumescent flame retardant compounded with a novel phosphorus-nitrogen flame retardant and APP.The flame retardancy,thermal decomposition process and mechanical properties of the flame-retarded PP were researched.The test results show that when the content of flame retardant is 30%,the oxygen index(OI) reaches to 32.3% and vertical combustion grade reaches to UL94 V-0 level,the tensile strength is 37.4 MPa,and the notched impact strength is 39.5 kJ/m2.The flame-retard...
Keywords:P-N flame retardant  Fire retardancy  Polypropylene  
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