| 4,4’-双(4-羟基苯甲氧基)-3,3’,5,5’-四甲基联苯二缩水甘油醚的合成与表征 |
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| 引用本文： | 张鹏云,陈卫东,杨文龙,李春新,刘茵.4,4’-双(4-羟基苯甲氧基)-3,3’,5,5’-四甲基联苯二缩水甘油醚的合成与表征[J].精细与专用化学品,2011,19(6):23-25. |
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| 作者姓名： | 张鹏云 陈卫东 杨文龙 李春新 刘茵 |
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| 作者单位： | 1. 甘肃省化工研究院,甘肃兰州,730020
2. 西北师范大学化学化工学院生态环境相关高分子材料教育部重点实验室,甘肃兰州,730070 |
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| 基金项目： | 甘肃省科技厅"科技支撑计划" |
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| 摘 要： | 以对羟基苯甲酸、3-溴丙烯、3,3′,5,5′-四甲基联苯二酚等为原料,通过间氯代过氧化苯甲酸氧化法合成4,4′-双(4-羟基苯甲氧基)3,3′,5,5′-四甲基联苯二缩水甘油醚,化合物结构用FT-IR和~1HNMR进行了表征。并对氢氧化钠用量,缚酸剂,氧化反应温度和时间的选择进行了讨论。
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| 关 键 词： | 4 4’-双(4-羟基苯甲氧基)-3 3’ 5 5’-四甲基联苯二缩水甘油醚 3 3’ 5 5’-四甲基联苯二酚 芳酯 合成 |
Synthesis and characterization of 4,4 '-bis(4-hydroxybenzoyloxy)-3,3',5,5'-tetramethylbiphenyl |
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| ZHANG Peng-yun,CHEN Wei-dong,YANG Wen-long,LI Chun-xin,LIU Yin.Synthesis and characterization of 4,4 '-bis(4-hydroxybenzoyloxy)-3,3',5,5'-tetramethylbiphenyl[J].Fine and Specialty Chemicals,2011,19(6):23-25. |
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| Authors: | ZHANG Peng-yun CHEN Wei-dong YANG Wen-long LI Chun-xin LIU Yin |
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| Affiliation: | 1.Gansu Research Institute of Chemical Industry,Lanzhou 730020,China; 2.Key Laboratory of Eco-environment-related polymer Materials of Ministry of Education,College of Chemistry and Chemical Engineering,Northwest Normal University,Lanzhou 730070,China) |
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| Abstract: | 4,4＇-bis（4-hydroxybenzoyloxy）-3,3＇,5,5＇-tetramethylbiphenyl was synthesized from p-hydroxybenzoic acid,3-bromopropene and 3,3＇,5,5＇-tetramethyl-diphenol,using m-choroperoxybenzoic acid as oxidant,and the structure of the synthesized product was characterized by means of IR and ~1HNMR.The effects of the amount of base,deacid reagent,the reaction temperature and time on the yield of the product were investigated. |
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| Keywords: | 4 4＇-bis（4-hydroxybenzoyloxy）-3 3＇ 5 5＇-tetramethylbiphenyl 3 3＇ 5 5＇-tetramethyl-diphenol aromatic ester synthesis |
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