| 聚四氟乙烯胶乳与碳黑粒子共凝聚行为的研究 |
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| 引用本文： | 朱耕宇,陈雪萍,陆世浚,李胜,翁志学.聚四氟乙烯胶乳与碳黑粒子共凝聚行为的研究[J].化学反应工程与工艺,2004,20(2):117-120. |
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| 作者姓名： | 朱耕宇 陈雪萍 陆世浚 李胜 翁志学 |
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| 作者单位： | 1. 浙江大学高分子工程研究所,浙江,杭州,310027
2. 浙江巨圣氟化学有限公司,浙江,衢州,324004 |
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| 摘 要： | 提出了用共凝聚的方法制备填充聚四氟乙烯(PTFE)的思想，以Al(NO3)3、CaCl2、KCI为凝聚剂进行PTFE分散乳液与碳黑粒子的共凝聚。考察了胶乳种类、凝聚温度、搅拌转速等对共凝聚过程的影响规律，初步探讨了共凝聚粒子的成粒机理。结果表明共凝聚粒子是疏水性的，粒子内碳黑分散均匀。
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| 关 键 词： | 聚四氟乙烯胶乳 碳黑粒子 共凝聚 成粒机理 疏水性 |
| 文章编号： | 1001-7631(2004)02-0117-04 |
| 修稿时间： | 2003年9月8日 |
Study on Hetero-coagulation of Poly(tetrafluoroethylene)Latex Particles and Carbon Black Particles |
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| Zhu Gengyu Chen Xueping Lu Shijun Li sheng Weng Zhixue.Study on Hetero-coagulation of Poly(tetrafluoroethylene)Latex Particles and Carbon Black Particles[J].Chemical Reaction Engineering and Technology,2004,20(2):117-120. |
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| Authors: | Zhu Gengyu Chen Xueping Lu Shijun Li sheng Weng Zhixue |
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| Abstract: | The idea of preparing filled poly(tretrafluorothyleneXPTFF) with hetero-coagulation method was introduced. Hetero-coagulation of PTFE latex particles and carbon black particles was studied with coagulation agents Al(NO3)3, CaCl2 and KCl. The influence of latex type, temperature and agitation speed on hetero-coagulation process were investigated. The mechanism of forming composite particles was discussed. The composite particles prepared by this means were hydropho-bic. The carbon black particles were dispersed in hetero-coagulated particles equably. |
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| Keywords: | hetero-coagulation poly (tetraf luoroethylene) carbon black |
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