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Morphology and Precipitation Kinetics of MnS in Low-Carbon Steel During Thin Slab Continuous Casting Process
作者姓名:YU  Hao  KANG  Yong-lin  ZHAO  Zheng-zhi  SUN  Hao
作者单位:[1]School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China [2]Jinan Iron and Steel Technical Center, Jinan Iron and Steel Group Co, Jinan 250101, Shandong, China
基金项目:国家自然科学基金 , 霍英东教育基金
摘    要:The morphology of manganese sulfide formed during thin slab continuous casting process in low-carbon steel produced by compact strip production (CSP) technique was investigated. Using transmission electron microscopy analysis, it was seen that a majority of manganese sulfides precipitated at austenite grain boundaries, the morphologies of which were spherical or close to the spherical shape and the size of MnS precipitates ranged from 30 nm to 100 nm. A mathematical model of the manganese sulfide precipitation in this process was developed based on classical nucleation theory. Under the given conditions, the starting and finishing precipitation temperatures of MnS in the continuous casting thin slab of the studied low-carbon steel are 1 189 ℃ and 1 171 ℃, respectively, and the average diameter of MnS precipitates is about 48 nm within this precipitation temperature range. The influences of chemical components and thermo-mechanical processing conditions on the precipitation behavior of MnS in the same process were also discussed.

关 键 词:薄板坯连铸  沉淀动力学  紧凑式带钢生产  TEM  CSP  低碳钢  MnS
收稿时间:2005-06-27

Morphology and Precipitation Kinetics of MnS in Low-Carbon Steel During Thin Slab Continuous Casting Process
YU Hao KANG Yong-lin ZHAO Zheng-zhi SUN Hao.Morphology and Precipitation Kinetics of MnS in Low-Carbon Steel During Thin Slab Continuous Casting Process[J].Journal of Iron and Steel Research,2006,13(5):30-36.
Authors:YU Hao  KANG Yong-lin  ZHAO Zheng-zhi  SUN Hao
Affiliation:1. Department of Materials Science, Montanuniversität Leoben, Franz-Josef-Strasse 18, 8700 Leoben, Austria;2. voestalpine Stahl GmbH, voestalpine-Strasse 3, 4020 Linz, Austria;3. Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Straße 1, 21502 Geesthacht, Germany
Abstract:The morphology of manganese sulfide formed during thin slab continuous casting process in low-carbon steel produced by compact strip production (CSP) technique was investigated. Using transmission electron microscopy analysis, it was seen that a majority of manganese sulfides precipitated at austenite grain boundaries, the morphologies of which were spherical or close to the spherical shape and the size of MnS precipitates ranged from 30 nm to 100 nm. A mathematical model of the manganese sulfide precipitation in this process was developed based on classical nucleation theory. Under the given conditions, the starting and finishing precipitation temperatures of MnS in the continuous casting thin slab of the studied low-carbon steel are 1 189 ℃ and 1 171 ℃, respectively, and the average diameter of MnS precipitates is about 48 nm within this precipitation temperature range. The influences of chemical components and thermo-mechanical processing conditions on the precipitation behavior of MnS in the same process were also discussed.
Keywords:morphology  thin slab continuous casting  precipitation kinetics  compact strip production  TEM
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