Synthesis and characterization of a new hyperbranched organic–inorganic solid polymer electrolyte with cyanuric chloride as a core element |
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| Authors: | Yu-Chi Pan Diganta Saikia Jason Fang Li-Duan Tsai George TK Fey Hsien-Ming Kao |
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| Affiliation: | aDepartment of Chemistry, National Central University, Chung-Li 32054, Taiwan, ROC;bDepartment of Fuel Cell Materials and Advanced Capacitors, Division of Energy Storage Materials and Technology, Material and Chemical Laboratories, Industrial Technology Research Institute, Hsin-Chu 300, Taiwan, ROC;cDepartment of Chemical and Materials Engineering, National Central University, Chung-Li 32054, Taiwan, ROC |
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| Abstract: | A new hyperbranched organic–inorganic hybrid electrolyte based on the use of 2,4,6-trichloro-1,3,5-triazine (cyanuric chloride, CC) as the coupling core to couple with oligo(oxyalkylene)-amines, followed by condensation with (3-glycidoxypropyl)-trimethoxysilane (GLYMO) and complexed with LiClO4, has been prepared and characterized. The Vogel–Tamman–Fulcher (VTF) like conductivity behavior is observed in the present organic–inorganic hybrid electrolytes with a maximum ionic conductivity value of 4.4 × 10−5 S cm−1 at 30 °C. Multinuclear NMR techniques are used to provide a microscopic view for the specific interaction between the polymer chains and Li+ cations and their dynamic behaviors. The results of 2D 1H–13C wide-line separation (WISE) and 7Li static line NMR width measurements divulge that the mobility of the 7Li cations is strongly related to a dynamic environment created by the polymer motion in the amorphous phase. The combined results of conductivity and 7Li pulse-gradient spin-echo (PGSE) NMR self-diffusion coefficient measurements reveal that the conductivity enhancement at low salt concentrations is mainly caused by the high mobility of the lithium cations. |
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| Keywords: | Organic&ndash inorganic hybrid electrolyte Ionic conductivity Differential scanning calorimetry Solid-state NMR |
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