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零价铁去除地下水硝酸盐的影响因素
引用本文:何珊,张永祥,唐超群,王慧峰.零价铁去除地下水硝酸盐的影响因素[J].水资源保护,2013,29(6):70-74.
作者姓名:何珊  张永祥  唐超群  王慧峰
作者单位:[1]北京工业大学建筑工程学院,北京100124 [2]北京市朝阳区水务局,北京100123
基金项目:国家水体污染控制与治理科技重大专项(2009ZX07212003)
摘    要:通过静态试验考察零价铁去除地下水硝酸盐的影响因素。结果表明:酸洗预处理可有效提高铁屑对NO-3-N的去除效果;NO-3-N初始质量浓度增加,NO-3-N去除率下降,平均去除速率升高;铁碳比为1∶2时,反应结束时NO-3-N质量浓度最低,且活性炭可吸附反应产物NH+4-N,降低反应产生的碱度;实际地下水去除NO-3-N效果显著,试验结束时pH维持在10以下,其共存离子对pH值的变化有一定缓冲作用。

关 键 词:零价铁  地下水  硝酸盐  影响因素
修稿时间:2013/11/25 0:00:00

Factors in using zero-valent iron to remove nitrate in groundwater
HE Shan,ZHANG Yongxiang,TANG Chaoqun,WANG Huifeng.Factors in using zero-valent iron to remove nitrate in groundwater[J].Water Resources Protection,2013,29(6):70-74.
Authors:HE Shan  ZHANG Yongxiang  TANG Chaoqun  WANG Huifeng
Affiliation:HE Shan;ZHANG Yongxiang;TANG Chaoqun;WANG Huifeng;College of Architecture and Civil Engineering,Beijing University of Technology;Water Service Bureau of Chaoyang District of Beijing City;
Abstract:Factors in using zero-valent iron to remove nitrate in groundwater were studied through static experiments.The results show that pickling pretreatment can effectively improve the removal effect of NO-3-N.The removal rate of NO-3-N declined and the average removal rate of NO-3-N increased when the initial concentration of NO-3-N increased.The concentration of NO-3-N was at its lowest at the end of the reaction when the ratio of Fe0/ C was 1: 2,and activated carbon could adsorb the reaction product NH+4-N,which reduced the alkalinity of reaction.The effect of NO-3-N reduction in actual groundwater was significant: the pH value was below 10 when the experiment was finished,and coexisting ions had a certain buffering effect on the change of the pH value.
Keywords:zero-valent iron  groundwater  nitrate  influencing factors
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