| 模板剂在介孔分子筛合成中的作用机理 |
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| 引用本文： | 王保国,张妍,李.模板剂在介孔分子筛合成中的作用机理[J].化学工业与工程,2005,22(2):115-119. |
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| 作者姓名： | 王保国 张妍 李 |
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| 作者单位： | 天津大学化工学院,教育部绿色转化与合成重点实验室,天津,300072 |
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| 基金项目： | 国家自然基金资助项目(29906006) |
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| 摘 要： | 以模板法合成分子筛不但能够有效的控制其介观结构,而且环境友好,操作简单,成本低廉,但由于反应在高压釜中进行,模板剂对分子筛合成的作用机理尚未被认清。本文总结了目前提出的可能的模板剂作用机理,并加以分类讨论,以对分子筛合成过程提供指导。
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| 关 键 词： | 介孔分子筛 模板 MCM41 表面活性剂 |
| 文章编号： | 1004-9533(2005)02-0115-05 |
| 修稿时间： | 2004年3月25日 |
Mechanism of Effect of Templates in the Formation of Mesoporous Sieves |
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| WANG Bao-guo,ZHANG Yan,LI Wei,ZHANG Jin-li,LIU Jia-qi.Mechanism of Effect of Templates in the Formation of Mesoporous Sieves[J].Chemical Industry and Engineering,2005,22(2):115-119. |
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| Authors: | WANG Bao-guo ZHANG Yan LI Wei ZHANG Jin-li LIU Jia-qi |
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| Affiliation: | WANG Bao-guo,ZHANG Yan,LI Wei,ZHANG Jin-li,LIU Jia-qiLaboratory for Green Chemical Transformation and Synthesis,Tianjin 300072,China) |
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| Abstract: | Using organic templates to direct the formation of the mesoporous molecular seives can not only control their meso-construction but also have the characters of easy-operations, less-pollution and low-cost, but the effect of the templates has not been known clearly yet. The possible mechanisms of the effect of the templates on the formation process have been summarized in order to guide the later studies. |
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| Keywords: | mesoporous molecular seive template MCM-41 surfactant |
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