Crystallization of AlPo4-5 from a system-1.5 (C3H7)3N.1.0Al2O3.1.0 P2O5. 40.0 H2O : Characterization of the products of crystallization |
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| Affiliation: | 1. College of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China;2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;3. Key Laboratory of Coal Gasification, Ministry of Education, East China University of Science and Technology, Shanghai 200237, China |
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| Abstract: | Crystallization of AlPO4-5 from a gel of composition 1.5 Pr3N (tripropylamine)· 1.0 Al2O3· 1.0 P2O5· 40.0 H2O has been investigated by carrying out the hydrothermal synthesis of the crystalline aluminophosphate in a closed stainless steel pressure bomb at 423 K for different durations of the crystallization (0–48 h). The solid products obtained during the course of crystallization have been characterized thoroughly for their crystallinity (as AlPO4-5), crystal size and morphology, N2-sorption capacity (at 78 K and relative pressure of 0.3), thermal analysis, site energy distribution by TPD of pyridine, acidity by chemisorption of pyridine at 673 K and also for their catalytic activity in cumene cracking and o-xylene isomerization reactions at 673 K. The aluminophosphate formed at the different crystallization periods differ from each other largely in these properties. The optimum crystallization period for the synthesis of AlPO4-5 is about 24 h. |
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