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等离子喷涂法纳米结构WC-12Co涂层的微结构与形成机理的研究
引用本文:李博宇,董星龙,刘圆圆,杨明川,刘方军.等离子喷涂法纳米结构WC-12Co涂层的微结构与形成机理的研究[J].材料工程,2006(6):40-45.
作者姓名:李博宇  董星龙  刘圆圆  杨明川  刘方军
作者单位:大连理工大学,三束国家重点实验室,辽宁,大连,116023;中国科学院,金属研究所,沈阳,110016;北京航空工艺研究所,北京,100024
基金项目:国防科技重点实验室基金
摘    要:使用独特的雾化干燥结合固定床技术合成WC-12Co纳米复合粉体,利用等离子喷涂法制备纳米结构WC-12Co涂层,通过X射线衍射、扫描电镜、透射电镜等分析手段对等离子喷涂纳米结构WC-12Co涂层进行显微结构分析.结果表明涂层中除了WC相,不仅有W2C,W等非WC/Co相的产生,还出现了CoxWyCz(Co3W9C4,Co3W3C),Co3C等相及非晶和孪晶组织,在此基础上本工作将对等离子喷涂纳米结构WC-12Co涂层的形成机理作初步的研究与讨论.

关 键 词:等离子喷涂  纳米复合粉体  纳米结构涂层  显微结构  形成机理
文章编号:1001-4381(2006)06-0040-06
收稿时间:2005-05-10
修稿时间:2005-09-15

Microstructure and Formation Mechanism of Nanostructured WC-12Co Coatings Deposited by Plasma Flame Spray
LI Bo-yu,DONG Xing-long,LIU Yuan-yuan,YANG Ming-chuan,LIU Fang-jun.Microstructure and Formation Mechanism of Nanostructured WC-12Co Coatings Deposited by Plasma Flame Spray[J].Journal of Materials Engineering,2006(6):40-45.
Authors:LI Bo-yu  DONG Xing-long  LIU Yuan-yuan  YANG Ming-chuan  LIU Fang-jun
Affiliation:1 State Key Laboratory for Materials Modification by Laser, Ion and Electron Beams, Dalian University of Technology, Dalian 116023, Liaoning, China; 2 Institute of Metal Research (IMR
Abstract:The precursor of WC-12Co nano-composite powder is synthesized by the larruping method of spray drying and fixed bed technique,nanostructured WC-12Co cermet coatings are deposited by plasma flame spray.Microstructure of nanostructured WC-12Co cermet coatings is evaluated by using X-ray diffraction(XRD),scanning electron microscopy(SEM) and transmission electron microscopy(TEM).The nano-composite WC-12Co powders generally contain WC and Co,whereas the phases W2C,W and Co3C,Co3W9C4,Co3W3C/amorphous binder phases based on Co and nano-twins occur in coatings,the mechanism of formation of nanostructured WC-12Co cermet coatings is discussed on the basis of the microstructure in this paper.
Keywords:plasma spray  nanocomposite powder  nanostructured coating  microstructure  mechanism of formation
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