Electrochemical copolymerization of indole and 3,4-ethylenedioxythiophene |
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Authors: | Jingkun?Xu Guangming?Nie Email author" target="_blank">Shusheng?ZhangEmail author Xuejun?Han Jian?Hou Shouzhi?Pu |
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Affiliation: | (1) College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong Province, 266042, People’s Republic of China;(2) Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang, Jiangxi Province, 330013, People’s Republic of China |
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Abstract: | The copolymerization of indole and 3,4-ethylenedioxythiophene (EDOT) was achieved electrochemically in acetonitrile containing lithium perchlorate as supporting electrolyte by direct anodic oxidation of the monomer mixtures on platinum and stainless steel electrodes. As-formed copolymers own both the advantages of polyindole (PIn) and poly (3,4-ethylenedioxythiophene) (PEDOT), i.e., good thermal stability, good electrochemical behavior, high conductivity and excellent ambient stability. The structure and morphology of the copolymer were investigated by UV-vis, infrared spectroscopy, thermal analysis and scanning electron microscopy (SEM), respectively. |
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