Synthesis,characterization, and flocculation characteristics of hydrolyzed and unhydrolyzed polyacrylamide grafted xanthan gum

The partial hydrolysis of xanthan gum‐g‐polyacrylamide was carried out in alkaline medium. Four grades of partially hydrolyzed products were synthesized by varying the reaction parameters. The neutralization equivalents of these products were determined by titration with standard sodium hydroxide solution. The flocculation characteristics of all the hydrolyzed graft copolymers and the unhydrolyzed xanthan gum‐g‐polyacrylamide were determined in 5 wt % iron ore and kaolin suspensions. The partially hydrolyzed product with neutralization equivalent of 1000 g showed better performance than that of other partially hydrolyzed products, but all hydrolyzed products exhibited poorer performance than that of the unhydrolyzed product in flocculation. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 1411–1419, 2004