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电弧喷涂Zn-Al-Mg-La-Ce涂层的耐腐蚀性能
作者姓名:邢士波  肖葵  李丽  李晓刚  刘安强  王恩清
作者单位:1. 北京科技大学新材料技术研究院, 北京 100083;
基金项目:国家科技基础条件平台建设计划;国家自然科学基金
摘    要:采用电弧喷涂法制备Zn-Al-Mg-La-Ce涂层,通过盐雾试验对涂层进行腐蚀,利用能谱分析、X射线衍射分析、扫描电镜观察、极化曲线以及电化学阻抗谱等手段对腐蚀前后的Zn-Al-Mg-La-Ce涂层进行了研究.结果表明:实验制备的Zn-Al-Mg-La-Ce涂层具有较好的自封闭效果,组织致密,在腐蚀过程中表面的微观孔隙能够被自身的腐蚀产物有效堵塞,涂层表面形成的致密腐蚀产物层能够阻止腐蚀的进一步发生.因此,Zn-Al-Mg-La-Ce涂层具有优异的耐蚀性能. 

关 键 词:锌铝合金    稀土    涂层    耐腐蚀性    喷涂
收稿时间:2011-08-09

Corrosion resistance of Zn-Al-Mg-La-Ce coatings by electric arc spraying
Affiliation:1. Institute of Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China;2. College of Mechanical and Electrical Engineering, Hebei University of Engineering; Handan 056038, China;3. Technology Center, Xinxing Ductile Iron Pipe Group Company, Handan 056300, China
Abstract:Zn-Al-Mg-La-Ce coatings were prepared by electric arc spraying,and their corrosion behavior was studied with salt spray test.The characteristics of the coatings before and after corrosion were investigated by energy dispersive spectrometry(EDS),X-ray diffraction(XRD),scanning electron microscopy(SEM),polarization curves,and electrochemical impedance spectroscopy.It is shown that the coatings have outstanding self-sealing effectiveness,and their structures are compact.During corrosion,microscopic pores on the surfaces of the coatings can be jammed with their own corrosion products,thus forming a dense corrosion product layer to prevent from further corrosion.Consequently,the corrosion resistance of Zn-Al-Mg-La-Ce coatings is superior to that of normal coatings. 
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