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The Conversion of Syngas to Liquid Fuels in a Dual-Bed Single Reactor Process
Authors:A Corsaro  T Wiltowski  D Juchelová
Affiliation:1. ENET – Energy Units for Utilization of non Traditional Energy Sources, V?B – Technical University of Ostrava, Ostrava-Poruba, Czech Republicagnieszka.corsaro@vsb.cz;3. Department of Mechanical Engineering and Energy Processes, Southern Illinois University, Carbondale, IL, USA;4. ENET – Energy Units for Utilization of non Traditional Energy Sources, V?B – Technical University of Ostrava, Ostrava-Poruba, Czech Republic;5. Department of Energy, Faculty of Mechanical Engineering, V?B – Technical University of Ostrava, Ostrava-Poruba, Czech Republic
Abstract:The effects of HZSM-5 temperature and weight hourly space velocity (WHSV) on conversion of syngas to liquid fuels were investigated in a single reactor process. The temperature of FT catalyst was constant (463 K), whereas the temperature of HZSM-5 varied (523, 573, 623 K). The value of WHSV ranged between 16 and 24 h?1. HZSM-5 addition suppressed the formation of CH4 and remarkably enhanced the formation of iso-C5-C12 paraffins. An increase of HZSM-5 temperature resulted in an enhancement of gaseous hydrocarbons, C18+ paraffins, and olefins. The optimal HZSM-5 temperature and WHSV were identified as 523 K and 16 h?1, respectively.
Keywords:Fischer-Tropsch synthesis  dual-bed  single reactor  liquid fuels  HZSM-5  cobalt
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