CO2 adsorption on systems involving ethylenediamine impregnated on nanoporous materials |
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Authors: | Thiago G Oliveira Marcelo J B Souza Ana C F Coriolano |
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Affiliation: | 1. Department of Chemistry, Federal University of Sergipe, S?o Cristóv?o, Brazil;2. Department of Chemical Engineering, Federal University of Sergipe, S?o Cristóv?o, Brazil;3. Potiguar University Laureate International Universities, School of Engeneering and Information Technology, Natal, Brazil |
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Abstract: | AbstractMCM-41 and MCM-48 materials were synthesized by the hydrothermal method, calcined and modified with ethylenediamine (EDA) by wet impregnation method. The X-ray diffraction patterns showed characteristic peaks of highly ordered MCM-41 and MCM-48 nanoporous materials, even after impregnation with amine. The MCM-41 and MCM-48 materials showed N2 adsorption isotherms type IV and BET surfaces areas higher than 1000?m2 g?1. The carbon dioxide adsorption tests were carried out at room temperature in a magnetic suspension microbalance. The materials presented good performance for CO2 capture, being favorable for applications where medium and high pressures are required. |
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Keywords: | CO2 adsorption ethylenediamine MCM-41 MCM-48 nanoporous materials |
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