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Cracking of Maya Crude Asphaltenes
Authors:F Trejo  J Ancheyta  A Noyola  V Sámano
Affiliation:1. Instituto Politécnico Nacional, CICATA-Legaria, México D. F., Méxicoftrejoz@ipn.mx;3. Instituto Mexicano del Petróleo, México D.F., México;4. Instituto Politécnico Nacional, CICATA-Legaria, México D. F., México;5. Instituto Mexicano del Petróleo, México D.F., México
Abstract:Cracking of Maya crude asphaltenes was carried out in a batch reactor at the following reaction conditions: temperature of 380–410°C, total pressure of 2 MPa, and asphaltenes/catalyst ratio of 5 g/g using NiMo commercial catalyst. n-hexadecane was used to keep asphaltenes dispersed and reaction time ranged from 0 to 60 min. The products were lumped into four fractions: asphaltenes, maltenes, gases, and coke. A kinetic model assuming pseudo–first-order parallel reactions was used to fit the experimental data.
Keywords:asphaltene cracking  lumping model  maltenes  coke  gases
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