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Photoluminescence properties of solid-state Tb^3+ doped NaY(MoO4)2
作者姓名:张子才  徐书超  李盼来  王志军  孙江  杨志平  庞立斌
作者单位:[1]Industrial & Commercial College, Hebei University, Baoding 071002, China; [2]Department of Foreign Language Teaching and Research, Hebei University, Baoding 071002, China; [3]College of Physics Science & Technology, Hebei University, Baoding 071002, China
基金项目:supported by the National Natural Science Foundation of China(No.50902042); the Natural Science Foundation of Hebei Province(Nos.A2014201035 and E2014201037); the Education Office Research Foundation of Hebei Province(Nos.ZD2014036 and QN2014085)
摘    要:A series of Tb^3+ doped Na Y(Mo O4)2 are synthesized by a solid-state reaction at 550 °C for 4 h, and their luminescent properties are investigated. The phase formation is carried out with X-ray powder diffraction analysis, and there is no other crystalline phase except Na Y(Mo O4)2. Na Y(Mo O4)2:Tb^3+ can produce the green emission under 290 nm radiation excitation, and the luminescence emission peak at 545 nm corresponds to the 5D4→7F5 transition of Tb^3+. The emission intensity of Tb^3+ in Na Y(Mo O4)2 is enhanced with the increase of Tb^3+ concentration, and there is no concentration quenching effect. The phenomena are proved by the decay curves of Tb^3+. Moreover, the Commission International de I'Eclairage(CIE) chromaticity coordinates of Na Y(Mo O4)2:Tb^3+ locate in the green region.

关 键 词:NaY  发光性能  固态  掺杂  X射线粉末衍射分析    反应合成  发光特性
收稿时间:2014-07-18
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