Influence of Cobalt Doping on the Physical Properties of Zn0.9Cd0.1S Nanoparticles |
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Authors: | Sonal Singhal Amit Kumar Chawla Hari Om Gupta Ramesh Chandra |
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Affiliation: | (1) Nanoscience Laboratory, Institute Instrumentation Center, Indian Institute of Technology Roorkee, Roorkee, 247667, India;(2) Department of Electrical Engineering, Indian Institute of Technology Roorkee, Roorkee, 247667, India; |
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Abstract: | Zn0.9Cd0.1S nanoparticles doped with 0.005–0.24 M cobalt have been prepared by co-precipitation technique in ice bath at 280 K. For the cobalt concentration >0.18 M, XRD pattern shows unidentified phases along with Zn0.9Cd0.1S sphalerite phase. For low cobalt concentration (≤0.05 M) particle size, d XRD is ~3.5 nm, while for high cobalt concentration (>0.05 M) particle size decreases abruptly (~2 nm) as detected by XRD. However, TEM analysis shows the similar particle size (~3.5 nm) irrespective of the cobalt concentration. Local strain in the alloyed nanoparticles with cobalt concentration of 0.18 M increases ~46% in comparison to that of 0.05 M. Direct to indirect energy band-gap transition is obtained when cobalt concentration goes beyond 0.05 M. A red shift in energy band gap is also observed for both the cases. Nanoparticles with low cobalt concentrations were found to have paramagnetic nature with no antiferromagnetic coupling. A negative Curie–Weiss temperature of −75 K with antiferromagnetic coupling was obtained for the high cobalt concentration. |
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Keywords: | Cobalt doping Paramagnetism Quantum confinement |
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