Optimization of synthesizing leucine-binding nano-sized magnetite by a two-step transformation |
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Authors: | Dong-Geun Lee Youn-Sang Bae Shao-Long Tie Mir Kim Ik-Sung Ahn Chang-Ha Lee |
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Affiliation: | (1) Department of Chemical Engineering, Yonsei University, 134 Shinchon-dong, Seodaemun-gu, Seoul, 120-749, Korea;(2) Department of Chemistry, South China Normal University, Guangzhou, 510631, P.R.China |
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Abstract: | The optimum conditions for synthesizing leucine (Leu)-binding nano-sized magnetite (NSM) particles by a two-step transformation
(TST) process were studied. The formation and magnetization of as-synthesized NSM particles were investigated through variation
of the acidity, the type of surface modifier, and the nature of the acid for pH adjustment. With increased acidity, the saturation
magnetization of the NSM particles decreased, but the amount of Leu coated on the surface of NSM particles increased. After
the influence of hydroxyl (OH−) groups on the surface of NSM particles was removed by using the dicarboxyl anion (C2O42−) as a ligand in the first step, Leu was successfully bound with NSM particles in the second step. However, when polyethylene
glycol (PEG) was used as a surface modifier, it was difficult to form the Leu-to-NSM particle complex. In terms of the acid
used to modify pH, H2SO4 was slightly less effective than HCl in achieving saturation magnetization because the coordination for SO42− anions is stronger than that of Cl− anions. The preparation of other amino acid-binding NSM particles can be optimized in an analogous manner. |
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Keywords: | Magnetite Two-step transformation Leucine Amino acid Nano-sized particle |
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