| 粉末注射成形低温热脱蜡的非等温动力学 |
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| 引用本文： | 李新军 吕海波. 粉末注射成形低温热脱蜡的非等温动力学[J]. 中国有色金属学报, 1997, 7(3): 112-115 |
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| 作者姓名： | 李新军 吕海波 |
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| 作者单位： | 中南工业大学粉末冶金研究所 |
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| 基金项目： | 中国有色金属工业总公司资助项目 |
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| 摘 要： | 利用热重法研究了石蜡在粉末注射成形中低温热脱除的非等温动力学。采用微分法和积分法来确定动力学参数。并推出石蜡在聚丙烯配方体系生坯中热脱除的动力学方程式为：－ｌｎ（１－ａ）＝Ａｅｘｐ（－Ｅ／ＲＴ）ｔｍ，（０＜ｍ＜１）。当ｍ＝０．２５时，为最可能的机理形式。热脱蜡的动力学控制步骤为石蜡在聚丙烯中的扩散过程。
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| 关 键 词： | 粉末注射成形 热脱蜡 非等温动力学 |
LOW TEMPERATURE THERMAL DEBINDING NON ISOTHERMAL KINETICS OF PARAFFIN WAX IN PIM |
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| Li Xinjun,Lu Haibo,Shi Xichang,Zhou Hong,Li Yuangao Powder Metallurgy Research Institute,Central South University of Technology,Changsha. LOW TEMPERATURE THERMAL DEBINDING NON ISOTHERMAL KINETICS OF PARAFFIN WAX IN PIM[J]. The Chinese Journal of Nonferrous Metals, 1997, 7(3): 112-115 |
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| Authors: | Li Xinjun Lu Haibo Shi Xichang Zhou Hong Li Yuangao Powder Metallurgy Research Institute Central South University of Technology Changsha |
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| Affiliation: | Li Xinjun,Lu Haibo,Shi Xichang,Zhou Hong,Li Yuangao Powder Metallurgy Research Institute,Central South University of Technology,Changsha 410083 |
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| Abstract: | Low temperature thermal debinding non isothermal kinetics of paraffin wax in PIM was studied by TG. And the kinetics parameters were determined by differential and integral methods. In the polypropylene based greenware, the most possible dewax kinetics equation was deduced to be -ln( 1-a)=A exp( -E/RT)t 1/4 . The dewax rate is controlled by the diffusion of paraffin wax in polypropylene. |
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| Keywords: | PIM thermal dewax non isothermal kinetics |
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