Dielectric and optical properties of Ni doped Na0.5Bi0.5TiO3 |
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Authors: | Suman Kalyan Pradhan SK De |
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Affiliation: | Department of Materials Science, Indian association for the Cultivation of Science, Jadavpur, Kolkata 700 032, India |
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Abstract: | Polycrystalline Ni doped Na.5Bi0.5TiO3 samples (Na0.5Bi0.5)Ti1-xNixO3, (x?=?0.5, 0.10, 0.15) have been prepared by solid state reaction. The appearance of the additional peak in X-ray diffraction pattern indicates the ordering of Ti4+ and Ni2+ ions. Polygonal grains are converted into flakes with an increase of Ni concentration. Replacement of Ti4+ by Ni2+ strongly modifies the relative contribution of two peaks in the Raman bands within 200–400?cm?1. Oxygen vacancy is observed in X-ray photoelectron spectrum to maintain charge neutrality due to aliovalent doping. Broad diffuse phase transition centered at the dielectric constant maximum indicates relaxor behaviour. Comparison between impedance and electric modulus spectrum suggests non-Debye relaxation. The ac conductivity follows the power law with the frequency exponent lies 0.52???0.72. The generation of holes by divalent Ni dopant at tetravalent Ti sites enhances optical band gap. |
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Keywords: | Grain size Dielectric property Impedance Raman-spectra |
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