Effect of sol-gel and solid-state synthesis techniques on structural,morphological and thermoelectric performance of Ca3Co4O9

Two methods of obtaining calcium cobalt oxide (Ca₃Co₄O₉) thermoelectric materials were studied: (I) solid state synthesis (SS) followed by high-energy ball-milling (HEBM) and (II) modified sol-gel method (SG). The obtained powders were heated at 900?°C for 12?h. They were subsequently compacted using spark plasma sintering (SPS). The crystal structure and morphology were characterized by X-ray diffraction and scanning electron microscopy. The calculated average crystallite sizes, before and after SPS, alter from 43 to 61?nm and from 38 to 41?nm, for the SS and SG powders, respectively. XRD studies of the obtained powders revealed presence of Co₃O₄ secondary phases, which turned into metallic cobalt after SPS. Thermoelectric measurements of sintered samples were performed in the range, 50–500?°C. The maximum Seebeck coefficient is 120?µV/K and 110?µV/K, for the SS and SG synthesized samples, respectively. The highest ZT was found to be 0.02 and 0.04 at 500?°C for the SS and SG samples, respectively.