Water vapor corrosion behavior and failure mechanism of plasma sprayed mullite/Lu2Si2O7-Lu2SiO5 coatings |
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| Authors: | Xunxun Hu Fangfang Xu Kunwei Li Gen Jin Yue Xu Xinqing Zhao |
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| Affiliation: | 1. School of Materials Science and Engineering, Beihang University, Beijing 100191, China;2. Guobiao (Beijing) Testing＆Certification Co., Ltd, 2 Xinjiekouwai Street, Beijing 100088, China;3. China National Institute of Standardization, 4 Zhichun Road, Beijing 100191, China;4. School of Chemistry, Beihang University, Beijing 100191, China |
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| Abstract: | A new coating with mullite as the inner layer and Lu2Si2O7-Lu2SiO5 (lutetium disilicate-lutetium monosilicate, LuDS-LuMS) composite as the top layer was designed and fabricated on the surface of porous SiC substrate by atmospheric plasma spraying (APS). The microstructure evolution, phase transformation, inter-diffusion and failure mechanism of the coated samples during steam cycling at 1450?°C were systemically investigated. The results indicated that the coated samples maintain weight gain and the average weight gain rate is 1.12?×?10?1 mg/cm2 h. The thermal expansion coefficient (CTE) mismatches between the coating and the substrate as well as between the two ceramic layers have produced a thermal mismatch stress. In addition, the chemical reaction induced the sintering of LuDS-LuMS layer, the amorphous-crystalline phase transformation and the transformation between LuDS and LuMS phases could result in aging stress. With the accumulation of thermal mismatch stress and aging stress, the through and horizontal cracks have appeared in the coating, leading to the coating failure. |
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| Keywords: | Lutetium silicates Environmental barrier coatings Inter-diffusion Corrosion Failure |
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