Electrically conductive carbon nanopipe-graphite nanosheet/polyaniline composites |
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Authors: | G Venkata Ramana Balaji Padya Vadali VSS Srikanth PK Jain G Padmanabham G Sundararajan |
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Affiliation: | aCenter for Carbon Materials, International Advanced Research Centre for Powder Metallurgy and New Materials (ARCI), Hyderabad 500005, India;bSchool of Engineering Sciences and Technology (SEST), University of Hyderabad, Hyderabad 500046, India |
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Abstract: | Carbon nanopipe (CNP)–graphite nanosheet (GNS)/polyaniline (PANI) composites are synthesized by in situ chemical oxidative polymerization. The structural analysis (electron microscopy, Raman and X-ray diffraction) reveal that PANI is uniformly coated on both CNP and GNS structures resulting in the formation of a network of uniform composite structures. Thermogravimetric analysis shows that CNP–GNS/PANI composites are thermally stable up to 300 °C; the polymeric backbone degrades above 300 °C. CNP–GNS/PANI composites doped with m-cresol, a mixture of camphor sulfonic acid (CSA) and chloroform, and a mixture of CSA and m-cresol are electrically conductive. The electrical conductivity strongly depends on the dopants and about six orders of variation in conductivity can be achieved through the choice of the dopant. |
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