Elaboration, by tape casting, and thermal characterization of a solid oxide fuel half-cell for low temperature applications |
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Authors: | Claire Bonhomme Sophie Beaudet-Savignat Caroline Pirovano |
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Affiliation: | a CNRS-ENSCI, Laboratoire Sciences des Procédés Céramiques et Traitements de Surface (SPCTS), UMR 6638, 47 Avenue Albert Thomas, 87065 Limoges, France b Laboratoire de Céramiques et Composants Avancés, CEA Le Ripault, BP 16, 37260 Monts, France c CNRS-ENSCL, Unité de Catalyse et de Chimie du Solide (UCCS), UMR 8181, BP 90108, 59652 Villeneuve d’Ascq, France |
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Abstract: | In the past years, a major interest has been devoted to decrease the working temperature of solid oxide fuel cell (SOFC) down to about 700 °C. In this respect, materials with a high ionic conduction at intermediate temperature have to be found and the processes to elaborate fuel cells, using these new materials, have to be developed.Apatite materials (La10−xSrx(SiO4)6O2±δ) are attractive candidates for solid electrolyte working at intermediate temperature. The ceramic powder was produced by solid state reaction and was tape cast to obtain green sheets.Concerning the cathode, a perovskite oxide (La1−xSrxMn1−yCoyO3−δ) has been chosen. The perovskite powder was also shaped by tape casting with the introduction of a pore forming agent (corn-starch) to obtain the required porosity in the sintered cathode.The co-firing of the electrolyte/cathode half-cell in air at 1400 °C-2 h gives a flat sample with a dense apatite (98.2%), a 42.7% porous cathode and neither delamination nor chemical reactivity between electrolyte and cathode materials.The dimensional behaviour of the electrolyte material is stable for an oxygen partial pressure ranging from 10−10 to 0.21 atmosphere, from room temperature to 700 °C. The thermal expansion coefficients of the electrolyte and cathode materials are rather close (Δα = 2.8 × 10−6 K−1) under air. |
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Keywords: | A Ceramics A Oxides C Electron microscopy C X-ray diffraction D Thermal expansion |
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