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Fabrication and Electromagnetic Properties of Conjugated NH2-CuPc@Fe3O4
Authors:Liang Yan  Zejun Pu  Mingzhen Xu  Renbo Wei  Xiaobo Liu
Affiliation:1.Research Branch of Advanced Functional Materials, School of Microelectronics and Solid-State Electronics, High Temperature Resistant Polymer and Composites Key Laboratory of Sichuan Province,University of Electronic Science and Technology of China,Chengdu,China;2.College of Materials Science and Engineering,Sichuan University of Science and Engineering,Zigong,China
Abstract:Conjugated amino-phthalocyanine copper containing carboxyl groups/magnetite (NH2-CuPc@Fe3O4) has been fabricated from FeCl3·6H2O and NH2-CuPc via a simple solvothermal method and its electromagnetic properties investigated. Scanning electron microscopy and transmission electron microscopy revealed that the NH2-CuPc@Fe3O4 was a waxberry-like nanomaterial with NH2-CuPc molecules effectively embedded in the interior of Fe3O4 particles in the form of beads. Introduction of NH2-CuPc effectively improved the complementarity between the dielectric and magnetic losses of the system, resulting in excellent electromagnetic performance. The minimum reflection loss of the as-prepared composite reached ?33.4 dB at 7.0 GHz for coating layer thickness of 4.0 mm and bandwidth below ?10.0 dB (90% absorption) of up to 3.8 GHz. These results indicate that introduction of NH2-CuPc results in a composite with potential for use as an electromagnetic microwave absorption material.
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