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废旧磷酸铁锂电池集流体分离与正极材料再生
引用本文:陈娟,张承龙,张西华,马恩. 废旧磷酸铁锂电池集流体分离与正极材料再生[J]. 有色金属工程, 2024, 0(1)
作者姓名:陈娟  张承龙  张西华  马恩
作者单位:上海第二工业大学,上海第二工业大学,上海第二工业大学,上海第二工业大学
基金项目:上海市逆向物流与供应链协同创新中心开放基金(A30YD230111-02)项目;国家重点研发计划“固废资源化”重点专项项目(2019YFC1904400)。
摘    要:利用NaOH碱溶去除集流体粘结剂高效分离LiFePO4正极材料,超声回收铝箔,利用固相法实现废旧LiFePO4的再生。当NaOH为0.8 mol/L,固液比20 mL/g,40℃反应10 min,正极材料的分离率达到99.78%,超声1 min后铝箔回收率为76%。机械活化500r/5h,添加10 wt%纯LiFePO4固相再生材料的最高放电比容量为新材料最高放电比容量的94.75%,60次循环测试后为初始放电比容量的88.62%。

关 键 词:废旧磷酸铁锂电池  碱溶-超声法  高效分离  固相再生  
收稿时间:2023-08-21
修稿时间:2023-09-24

Waste lithium iron phosphate battery current collectors separation and cathode material regeneration
CHEN Juan,ZHANG Cheng-long,ZHANG Xi-hua and MA En. Waste lithium iron phosphate battery current collectors separation and cathode material regeneration[J]. Nonferrous Metals Engineering, 2024, 0(1)
Authors:CHEN Juan  ZHANG Cheng-long  ZHANG Xi-hua  MA En
Affiliation:Shanghai Polytechnic University,Shanghai Innovation Center of Reverse Logistics and Supply Chain,Shanghai Polytechnic University,Shanghai Innovation Center of Reverse Logistics and Supply Chain,Shanghai Polytechnic University,Shanghai Innovation Center of Reverse Logistics and Supply Chain,Shanghai Polytechnic University,Shanghai Innovation Center of Reverse Logistics and Supply Chain
Abstract:The LiFePO4 cathode material was efficiently separated by NaOH alkaline solution-removing fluid collecting binder, and the aluminium foil was recovered by ultrasound. The waste LiFePO4 was regenerated by the solid phase method. When NaOH was 0.8 mol /L, the solid-liquid ratio was 20 mL/g, and the reaction was carried out at 40℃ for 10 min, the separation rate of anode material reached 99.78%, and the recovery rate of aluminium foil was 76% after 1 min of ultrasound. After mechanical activation of 500r/5h, the highest specific discharge capacity of 10 wt% pure LiFePO4 solid phase regenerated material was 94.75% of the highest specific discharge capacity of the new material, and the capacity retention rate was 88.62% after 60 cycles of test.
Keywords:Waste lithium iron phosphate battery   Alkali solution-ultrasonic method   High efficiency separation  Solid phase regeneration  
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