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纳米SiC改性氰酸酯树脂的性能及其作用机理研究
引用本文:张学英,张文根,祝保林,王君龙,梁国正. 纳米SiC改性氰酸酯树脂的性能及其作用机理研究[J]. 中国塑料, 2009, 23(1): 43-46. DOI: 10.19491/j.issn.1001-9278.2009.01.009
作者姓名:张学英  张文根  祝保林  王君龙  梁国正
作者单位:1.渭南师范学院复合材料研究所,陕西 渭南 714000;2.西北工业大学理学院,陕西 西安 710072
摘    要:采用模塑成型法制备氰酸酯树脂(CE)/纳米SiC复合材料,通过冲击强度和弯曲强度测试,分别考察了纳米SiC及其经偶联剂KH-560表面处理后对CE/纳米SiC复合材料力学性能的影响,并通过理论分析探讨了其作用机理。结果表明,纳米SiC能够有效地改善复合材料的力学性能,而经KH-560表面处理的纳米SiC能进一步提高复合材料的冲击强度和弯曲强度;当纳米SiC含量为1 %时,CE/纳米SiC和CE/纳米SiC/KH-560复合体系的冲击强度分别提高了73.66 %和86.26 %,弯曲强度分别提高了20.85 %和29.56 %。

关 键 词:氰酸酯树脂  纳米碳化硅  力学性能  改性机理  
收稿时间:2008-09-26

Research on Modification and Function Mechanism of Cyanate Ester Resin by Nano-SiC
ZHANG Xue-ying,ZHANG Wen-gen,HU Bao-lin,WANG Jun-long,LIANG Guo-zheng. Research on Modification and Function Mechanism of Cyanate Ester Resin by Nano-SiC[J]. China Plastics, 2009, 23(1): 43-46. DOI: 10.19491/j.issn.1001-9278.2009.01.009
Authors:ZHANG Xue-ying  ZHANG Wen-gen  HU Bao-lin  WANG Jun-long  LIANG Guo-zheng
Affiliation:1.Composite Research Institution, Weinan Teachers College, Weinan 714000, China; 2.School of Sciences, Northwest Polytechnical University, Xi’an 710072, China
Abstract:The cyanate ester resin (CE)/nano-SiC composites were prepared by moulding method. Influences of nano-SiC and its surface treatment on the static mechanical properties of CE were characterized through impact and flexural strengths. The reinforcement mechanism was discussed. It indicated that nano-SiC efficiently improved the static mechanical properties of CE, and the surface treatment with KH-560 of nano-SiC further improved the impact and flexural strengths. When the content of nano-SiC was 1 %, the impact and flexural strengths of the composites containing untreated nano-SiC increased 73.66% and 20.85%, those containing KH-560 modified nano-SiC increased 86.26% and 29.56%, respectively, based on neat CE resin.
Keywords:cyanate ester resin  nano-SiC  mechanical properties  modified mechanism  
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