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Efficient Enantioselective Hydrosilylation of Aryl Ketones Catalyzed by a Chiral BINAP‐Copper(I) Catalyst‐Phenyl(methyl)silane System |
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| Authors: | Jean Thomas Issenhuth Samuel Dagorne Stphane Bellemin‐Laponnaz |
| Abstract: | The Cu(I)‐chiral diphosphine (BINAP) system was found to efficiently catalyze the hydrosilylation of aryl alkyl ketones with excellent enantioselectivities by using phenyl(methyl)silane as stoichiometric hydride source. |
| Keywords: | asymmetric catalysis copper hydride hydrosilylation |