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PVT-Properties of branched main-chain polymer liquid crystals
Authors:Michael Hess
Affiliation:(1) Department of Physical Chemistry, Gerhard-Mercator-University, 47048 Duisburg, Germany,
Abstract:The thermodynamic properties of a series of longitudinal (main-chain) polymer liquid crystals were investigated by analysis of their pressure–volume–temperature characteristics. It is possible to describe the behaviour of theses semi-rigid polymers above the glass-transition temperature with excellent accuracy using a mathematically very simple equation of state: the Hartmann Equation. Electronic Publication
Keywords:Polymer Liquid Crystals P–  V–  T measurements Hartmann equation of state
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