From Mechanistic and Kinetic Understanding of Heterogeneously Catalyzed Reactions to Tuning Catalysts Performance

A number of strategies for tuning performance of heterogeneously catalyzed reactions are being explored. They comprise: (1) optimizing reactor operation based on the knowledge of reaction mechanism and kinetics, (2) application of well-defined nano-sized metal nanoparticles for preparation of supported catalysts, and (3) combining complementary reactions into one process via a proper reactor design. The present mini review demonstrates their potential for conversion of C₃–C₄ alkanes to the corresponding alkenes, oxidative functionalization of methane, Fischer–Tropsch reaction and HCl oxidation to Cl₂ (Deacon process).