Optimization of formic acid hydrolysis of corn cob in xylose production |
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Authors: | Tao Zhu Pingli Li Xiaowei Wang Wandian Yang Heying Chang Sai Ma |
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Affiliation: | 1. School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, P. R. China
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Abstract: | Dilute acid pretreatment of lignocellulosic material is one of the significant steps in a biorefinery. We used response surface methodology to determine the important factors of formic acid concentration (2%–6% wt%), treatment time (30–150 min), reaction temperature (120–160 °C), and liquid to solid ratio (3–11 mL/g) on dilute acid hydrolysis of corn cob to produce xylose. A xylose yield of 81.6% and selectivity of 15.1 g/g were achieved under the optimal conditions (5% acid concentration, 150 min, 135 °C, and 7 mL/g liquid to solid ratio). The addition of trivalent salts (FeCl3, Fe(NO3)3, and Fe2(SO4)3) to the reaction system enhanced the xylose yield but decreased selectivity. The FeCl3 concentration over 0.75 mol/L had a negative effect on xylose production. |
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