| Thermodynamic Assessment of DyCl3-MCl （M= Na, K, Rb, Cs） Systems |
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| 引用本文： | 孙益民 孟祥珍 李俊 袁顺香 马芝森 乔芝郁. Thermodynamic Assessment of DyCl3-MCl （M= Na, K, Rb, Cs） Systems[J]. 中国稀土学报(英文版), 2007, 25(1): 36-41. DOI: 10.1016/S1002-0721(07)60041-6 |
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| 作者姓名： | 孙益民 孟祥珍 李俊 袁顺香 马芝森 乔芝郁 |
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| 作者单位： | [1]Institute of Chemistry and Materials Science, Anhui Normal University, Wuhu 241000, China [2]Department of Physical Chemistry, University of Science and Technology Beijing , Beijing 100083, China |
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| 基金项目： | Project supported by Key Project Foundation of Natural Science of Anhui Education Committee （2005KJ016ZD） |
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| 摘 要： | Using the CALPHAD （Calculation of Phase Diagram） technique, the DyCl3-MCl （M = Na, K, Rb, Cs） systems were optimized and calculated. The modified quasi-chemical model in the pair approximation for short-range ordering was used to describe the Gibbs energies of the liquid phase in these systems. From the measured phase diagram data and experimental thermodynamic properties, a series of thermodynamic functions were optimized base on an interactive computer-assisted analysis. The optimized parameters and the experimental data were thermodynamically self-consistent. The optimized results were discussed.
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| 关 键 词： | 稀土元素 热力学 氯化镝 相图 拟化学模式修饰 |
| 文章编号： | 1002-0721（2007）01-0036-06 |
| 收稿时间： | 2006-03-04 |
| 修稿时间： | 2006-03-042006-05-20 |
Thermodynamic Assessment of DyCl3-MCl (M = Na, K, Rb, Cs) Systems |
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| Sun , Meng Xiangzhen, Li Jun, Yuan Shunxiang, Ma Zhisen,Qiao Zhiyu. Thermodynamic Assessment of DyCl3-MCl (M = Na, K, Rb, Cs) Systems[J]. Journal of Rare Earths, 2007, 25(1): 36-41. DOI: 10.1016/S1002-0721(07)60041-6 |
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| Authors: | Sun Meng Xiangzhen Li Jun Yuan Shunxiang Ma Zhisen Qiao Zhiyu |
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| Affiliation: | 1. Institute of Chemistry and Materials Science, Anhui Normal University, Wuhu 241000, China; 2. Department of Physical Chemistry, University of Science and Technology Beijing , Beijing 100083, China |
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| Abstract: | Using the CALPHAD (Calculation of Phase Diagram) technique, the DyCl3-MCl (M=Na, K, Rb, Cs) systems were optimized and calculated. The modified quasi-chemical model in the pair approximation for short-range ordering was used to describe the Gibbs energies of the liquid phase in these systems. From the measured phase diagram data and experimental thermodynamic properties, a series of thermodynamic functions were optimized base on an interactive computer-assisted analysis. The optimized parameters and the experimental data were thermodynamically self-consistent. The optimized results were discussed. |
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| Keywords: | phase diagram modified quasi-chemical mode thermodynamic functions rare earths |
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