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Antimicrobial polyurethane coatings based on ionic liquid quaternary ammonium compounds
Authors:MB YagciS Bolca  JPA HeutsW Ming  G de With
Affiliation:a Laboratory of Materials and Interface Chemistry, Eindhoven University of Technology, 5600 MB Eindhoven, The Netherlands
b Laboratory of Microbial Ecology and Technology (LabMET), Faculty of Bioscience Engineering, Ghent University, B-9000, Ghent, Belgium
c Laboratory of Polymer Chemistry, Eindhoven University of Technology, 5600 MB Eindhoven, The Netherlands
d Nanostructured Polymers Research Center, Materials Science Program, University of New Hampshire, Durham, NH03824, USA
Abstract:The antimicrobial effect of ionic liquids (ILs) as comonomers in polyurethane surface coatings was investigated. Ionic liquid-containing coatings were prepared from a hydroxyl end-capped liquid oligoester and a triisocyanate crosslinker. Three different commercially available hydroxyl end-capped ionic liquids were covalently incorporated into the coatings in order to end up with antimicrobial polyurethane films. The ionic liquids used in this study were chosen because of their structural similarities to other antimicrobial quaternary ammonium compounds (QACs). Prepared films have been examined against both Gram-positive Staphylococcus aureus and Gram-negative Escherichia coli type bacteria, and showed strong antimicrobial activity.
Keywords:Antimicrobial coating  Ionic liquid  Contact killing
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