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季戊四醇和二季戊四醇结晶相平衡研究
引用本文:喻仕瑞,余晓清,陈天祥.季戊四醇和二季戊四醇结晶相平衡研究[J].四川化工,2010,13(2):12-14.
作者姓名:喻仕瑞  余晓清  陈天祥
作者单位:贵州大学化学与化工学院,贵州贵阳,550001
摘    要:季戊四醇合成一般采用结晶法,合成反应液中往往有二季戊四醇副产物生成。本文用综合法研究季戊四醇和二季戊四醇在水中的相平衡,绘制了其饱和曲线与过饱和曲线,为在水溶液中分离提纯季戊四醇提供热力学参考依据。

关 键 词:季戊四醇  二季戊四醇  结晶  相平衡

Study on Crystallization Phase Equilibrium of the Pentaerythritol and Dipentaerythritol in Solution
Yu Shirui,Yu Xiaoqing,Chen Tianxiang.Study on Crystallization Phase Equilibrium of the Pentaerythritol and Dipentaerythritol in Solution[J].sichuan chemical industry,2010,13(2):12-14.
Authors:Yu Shirui  Yu Xiaoqing  Chen Tianxiang
Affiliation:(School of Chemistry and Chemical Engineering ,Guizhou University ,Guiyang 550001' ,Guizhou ,China)
Abstract:Synthesis of pentaerythritol used crystallization method in commonly , with by-products of dipentaerythrltol in reaction solution. This paper study on crystallization phase equilibrium of the pentaerythritol and dipentaerythritol in solution by synthesis method, and drawing its saturation curve and oversaturation curves. It provides thermodynamic reference for Separation purification of pentaerythritol in solution.
Keywords:pentaerythritol  dipentaerythritol  crystallize  phase equilibrium
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