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LiCoO2的TiO2包覆原理探索研究
引用本文:孙文彬,谢嫚,张联齐,陈人杰,刘兴江.LiCoO2的TiO2包覆原理探索研究[J].电源技术,2012,36(1):75-78.
作者姓名:孙文彬  谢嫚  张联齐  陈人杰  刘兴江
作者单位:1. 北京理工大学 化工与环境学院,北京 100081;中国电子科技集团公司第十八研究所,天津300381
2. 北京理工大学 化工与环境学院,北京,100081
3. 中国电子科技集团公司第十八研究所,天津,300381
摘    要:文献中对LiCoO2材料的表面包覆已经进行大量的报道,清晰显示LiCoO2的表面改性对材料循环性能产生了重要正性效应。然而,材料的包覆原理和作用机制直到目前仍然模糊不清,没有一个确定统一定论。采用溶胶-凝胶法,结合TiO2与LiCoO2体相反应的研究结果,详细地研究了TiO2对LiCoO2的包覆效应,建议了可能包覆原理和作用机制。

关 键 词:TiO2  LiCoO2  表面包覆  锂离子电池

Mechanism of TiO2 coating on LiCoO2
SUN Wen-bin , XIE Man , ZHANG Lian-qi , CHEN Ren-jie , LIU Xing-jiang.Mechanism of TiO2 coating on LiCoO2[J].Chinese Journal of Power Sources,2012,36(1):75-78.
Authors:SUN Wen-bin  XIE Man  ZHANG Lian-qi  CHEN Ren-jie  LIU Xing-jiang
Affiliation:1.Department of Chemical Engineering and Environment,Beijing Institute of Technology,Beijing 100081,China;2.Tianjin Institute of Power Sources,Tianjin 300381,China)
Abstract:Recently,a lot of efforts were dedicated to the investigation on TiO2-coated LiCoO2,indicating that the surface-coating produced remarkable improvement in cycle ability.However,the working mechanism of surface-coating was still unclear so far.In this work,in combination with the study on the phase thermal stability of coating materials against LiCoO2,TiO2-coated LiCoO2 was investigated in detail by a sol-gel coating route and further a possible coating process and working mechanism of coating materials were proposed.
Keywords:TiO2  LiCoO2  surface-coating  lithium ion battery
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