Department of Chemistry University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA
General Portland Inc. Research and Development 4241 Sigma Road, Dallas, Texas 75240, USA
Abstract:
Small quantities (<2%) of various metal oxides are incorporated into the lattice of β-C2S during the high temperature preparation. The effect which these stabilizers have on the hydration rate is examined. A model involving the charge/radius ratio of the metal ion is developed to explain altered hydration rates. This charge/ radius ratio model also proves useful in describing the crystal-chemical stabilization of β-C2S. In addition, the solubility of Cr2O3 in β-C2S is determined by a novel differential thermal analysis technique.